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Ionic Liqids in Organic Synthesis: The Pummerer Reaction
Author(s) -
Hou ReiSheu,
Wang HueyMin,
Chang YaWen,
Chen LingChing
Publication year - 2006
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200600055
Subject(s) - chemistry , hexafluorophosphate , ionic liquid , pummerer rearrangement , adduct , imide , organic chemistry , medicinal chemistry , catalysis , acetic anhydride
Pummerer‐type reaction was carried out with α‐acyl sulfides and phenyliodine(III) bis(trifluoroacetate) (PIFA) instead of α‐acyl sulfoxides in the room temperature ionic liquid 1‐ n ‐butyl‐3‐methylimidazolium hexafluorophosphate [bmim][PF 6 ] under mild conditions to give the ene adducts 3 in good yields.
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