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One Pot Preparation of Amides from Azo Compounds by Sm/TiCl 4
Author(s) -
Li Xue,
Zhang YongMin
Publication year - 2005
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200500175
Subject(s) - chemistry , aniline , organic chemistry , polymer chemistry
Azo compounds were conveniently reduced by a system consisting of Sm/TiCl 4 to produce aniline anions. This anion species reacted smoothly with aliphatic acyl chlorides or acid anhydrides to afford corresponding amides under mild and neutral conditions.