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Isomerization of 4‐Methyl‐1‐pentene and 1‐Hexene Catalysed by Macroporous Ion Exchange Resin: A Kinetic Study
Author(s) -
Mitkova Magdalena,
Kurtev Kurti
Publication year - 2005
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200500170
Subject(s) - isomerization , chemistry , propene , kinetic energy , 1 hexene , photochemistry , pentene , atmospheric pressure , catalysis , ion , hexene , ion exchange resin , kinetics , organic chemistry , ethylene , physics , oceanography , quantum mechanics , geology
Abstract The isomerization of 4‐methyl‐1‐pentene and 1‐hexene, thermodynamically the most unstable propene dimers, was studied. The isomerization was catalyzed by strongly acidic ion exchange resins in the temperature range of 362‐384 K and under atmospheric pressure. The reaction scheme and kinetic equations, which best fit the experimental data are given.