Syntheses, Structures and Spectroscopic Studies of Silver(I) Coordination Polymers Bridged by Flexible Bidentate Ligands | Zendy

Suen MawCherng | Zendy; Tsai HuiAn | Zendy; Wang JuChun | Zendy

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Syntheses, Structures and Spectroscopic Studies of Silver(I) Coordination Polymers Bridged by Flexible Bidentate Ligands

Author(s) -

Suen MawCherng,

Tsai HuiAn,

Wang JuChun

Publication year - 2005

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.200500154

Subject(s) - chemistry , denticity , crystallography , crystal structure , propane , solid state , stereochemistry , polymer , organic chemistry

The reaction of Ag 2 SO 4 and bpp (bpp = 1,3‐bis(4‐pyridyl)propane) in H 2 O afforded the complex [Ag 2 (bpp) 2 (SO 4 ) · 6.5H 2 O·CH 3 OH] n , 1. The IR and TGA have been recorded and the structure has been determined. Crystal data for 1: Space group C 2 /c, a = 17.885(4), b = 25.230(6), c = 8.832(2) Å, β = 105.437(4)°. V = 3841(1) Å 3 , Z = 8 with final residuals R1 = 0.0710 and wR2 = 0.1620. The complex shows a three‐dimensional supramoleclar structure constructed with two‐dimensional infinite [Ag 2 (bpp) 2 ] n sheetlike layers pillared by Ag‐Ag interactions and Ag····O (SO 4 ) interactions in the solid state.

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