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1,3‐Dichloro‐5,5‐dimethylhydantoin (DCDMH) as a New Oxidizing Agent for the Facile and Selective Oxidation of Oximes to Their Carbonyl Compounds
Author(s) -
Khazaei Ardeshir,
Manesh Abbas Amini
Publication year - 2005
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200500142
Subject(s) - chemistry , oxidizing agent , organic chemistry , combinatorial chemistry
Oximes are converted to the parent carbonyl compounds in good yields when treated with 1,3‐dichloro‐5,5‐dimethylhydantoin (DCDMH) ( 1 ). An optimized procedure has been developed; the simple work‐up minimizes loss of product and oximes have been selectively oxidized in the presence of alcohols and alkenes.