Subsolidus Binary Phase Diagrams of C 10 ZnCl‐C 16 ZnCl and C 12 ZnCl‐C 16 ZnCl | Zendy

Wu Kezhong | Zendy; Zhang Chaoxing | Zendy; Li Yajuan | Zendy; Liu Xiaodi | Zendy

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Subsolidus Binary Phase Diagrams of C 10 ZnCl‐C 16 ZnCl and C 12 ZnCl‐C 16 ZnCl

Author(s) -

Wu Kezhong,

Zhang Chaoxing,

Li Yajuan,

Liu Xiaodi

Publication year - 2005

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.200500007

Subject(s) - chemistry , phase diagram , eutectic system , differential scanning calorimetry , crystallography , phase (matter) , solid solution , binary number , inorganic chemistry , thermodynamics , organic chemistry , microstructure , physics , arithmetic , mathematics

Decylammonium tetrachlorozincate (n‐C 10 H 21 NH 3 ) 2 ZnCl 4 (C 10 ZnCl), dodecylammonium tetrachlorozincate (n‐C 12 H 25 NH 3 ) 2 ZnCl 4 (C 12 ZnCl) and hexadecylammonium tetrachlorozincate (n‐C 16 H 33 NH 3 ) 2 ZnCl 4 ‐(C 16 ZnCl) were synthesized and a series of their mixtures C 10 ZnCl‐C 16 ZnCl and C 12 ZnCl‐C 16 ZnCl were prepared. The experimental binary phase diagrams of C 10 ZnCl‐C 16 ZnCl and C 12 ZnCl‐C 16 ZnCl were established by means of differential scanning calorimetry (DSC), IR and X‐ray diffraction. In the phase diagram a stable solid compound and two eutectoid invariants were observed. It is noticeable that the phase diagram contains solid solution ranges.

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