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Ene Reaction of Pummerer‐type Reaction Intermediate of (Methylthio)Acetonitrile: Synthesis of Dienenitriles
Author(s) -
Huang HsinYu,
Wang HueyMin,
Kang IouJiun,
Chen LingChing
Publication year - 2003
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200300149
Subject(s) - chemistry , acetonitrile , adduct , ene reaction , pummerer rearrangement , medicinal chemistry , organic chemistry , catalysis , acetic anhydride
Pummerer‐type reaction intermediate 2 of (methylthio)acetonitrile ( 1 ) has been found to react with 1‐alkenes to afford ene adducts 3 . Dienenitriles ( 4 ) were synthesized from adducts 3 .