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Volumetric Properties and Volumetric Interaction Parameters of the CsCl‐saccharides (D‐glucose, D‐fructose)‐water Solutions at 298.15 K
Author(s) -
Jiang Yucheng,
Gao Shiyang,
Xia Shuping,
Wang Jianji,
Zhuo Kelei,
Hu Mancheng
Publication year - 2003
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200300133
Subject(s) - chemistry , dilution , aqueous solution , fructose , molar volume , volume (thermodynamics) , molar , additive function , analytical chemistry (journal) , chromatography , thermodynamics , organic chemistry , medicine , physics , mathematics , dentistry , mathematical analysis
Densities have been measured for the CsCl‐saccharide (D‐glucose, D‐fructose)‐water systems at 298.15 K. These data were used to calculate the apparent molar volume of CsCl ( V φ,E ) and the saccharides ( V φ,S ), and the infinite dilution apparent molar volume V φ,E 0 and V φ,S 0 in the studied solutions. In addition, the standard transfer volume Δ t V φ,E 0 of CsCl from water to aqueous saccharides solutions, and Δ t V φ,S 0 of saccharides from water to CsCl solutions have been evaluated and discussed using the structural interaction model. The volumetric interaction parameters for CsCl with saccharide in water were obtained and analyzed by the group additivity principle and the stereochemistry of the saccharide molecules.