Palladium(II) Complexes Containing P∼N∼O Donors. Preparation and Reactivity | Zendy

Shi PingYung | Zendy; Liu YiHong | Zendy; Peng ShieMing | Zendy; Liu ShiuhTzung | Zendy

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Palladium(II) Complexes Containing P∼N∼O Donors. Preparation and Reactivity

Author(s) -

Shi PingYung,

Liu YiHong,

Peng ShieMing,

Liu ShiuhTzung

Publication year - 2003

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.200300012

Subject(s) - chemistry , palladium , reactivity (psychology) , phosphine , carbon monoxide , olefin fiber , ligand (biochemistry) , styrene , medicinal chemistry , ether , catalysis , polymer chemistry , copolymer , organic chemistry , medicine , biochemistry , polymer , alternative medicine , receptor , pathology

Palladium complexes [( P∼N∼O )PdR]BF 4 containing imine‐phosphine‐ether tridentate donor were prepared. The behavior of an ether donor, a hemi‐labile one, influences the coordination mode of a carbon ligand around the metal center. Reaction of excess styrene with [( P∼N∼O )PdMe]BF 4 results in the formation of [( P∼N∼O )Pd(η 3 ‐CH(CH 3 )C 6 H 5 )]BF 4 , which is characterized by spectral and crystal structural determination. Copolymerization of olefin and carbon monoxide catalyzed by [( P∼N∼O )PdMe]BF 4 is addressed.

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