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Electroanalytical Kinetic and Diffusion Studies for the Reduction of 4‐Cyano‐3‐substituted Sydnones
Author(s) -
Wang LaiHao,
Tien HsienJu
Publication year - 2003
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200300003
Subject(s) - chemistry , supporting electrolyte , electrochemistry , polarography , dropping mercury electrode , kinetics , hanging mercury drop electrode , mercury (programming language) , inorganic chemistry , solvent , drop (telecommunication) , electrode , electrolyte , organic chemistry , voltammetry , telecommunications , physics , quantum mechanics , computer science , programming language
The electrochemical reduction mechanism of five 4‐cyano‐3‐substituted sydnones was investigated at a hanging mercury drop electrode by cyclic, linear sweep and differential pulse voltammetric methods in Britton‐Robinson buffer (pH 1.68–11.76). The electrode kinetics of 4‐cyano‐3‐(p‐tolyl)sydnone were studied in protic and aprotic solvent containing different tetra‐alkylammonium salts supporting electrolytes, respectively.