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Preparation and Reactivity of Mo(NCMe)(η 2 ‐C 2 Ph 2 ) 2 (η 4 ‐C 4 Ph 4 )
Author(s) -
Chang SuChin,
Yeh WenYann,
Lee GeneHsiang,
Peng ShieMing
Publication year - 2002
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200200050
Subject(s) - chemistry , acetonitrile , reactivity (psychology) , x ray crystallography , trimethylphosphine , diphenylacetylene , solvent , inorganic chemistry , medicinal chemistry , nuclear chemistry , crystallography , crystal structure , diffraction , organic chemistry , catalysis , medicine , physics , alternative medicine , pathology , optics
Reaction of Mo(CO)(η 2 ‐C 2 Ph 2 ) 2 (η 4 ‐C 4 Ph 4 ) and Me 3 NO in acetonitrile solvent affords Mo(NCMe)(η 2 ‐C 2 Ph 2 ) 2 (η 4 ‐C 4 Ph 4 ) 1 . Compound 1 reacts with trimethylphosphine to produce Mo(PMe 3 )(η 2 ‐C 2 Ph 2 ) 2 (η 4 ‐C 4 Ph 4 ) 2 , or reacts with diphenylacetylene to produce (η 5 ‐C 5 Ph 5 ) 2 Mo 3 and Mo(η 2 ‐O 2 CPh)(η 4 ‐C 4 Ph 4 H)(η 4 ‐C 4 Ph 4 ) 4 . The molecular structures of 1, 2 and 4 have been determined by an X‐ray diffraction study.
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