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Preparation and Structure of [(η 5 ‐C 5 H 5 )Fe(CO){C(O)Ph} 2 ] 2 Li 2 (2,2′‐Bipyridine): A Sequential Treatment of Nucleophile Followed by Lewis Base
Author(s) -
Liu LingKang,
Peng James,
Huang Candice
Publication year - 2002
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200200047
Subject(s) - chemistry , nucleophile , electrophile , lewis acids and bases , bipyridine , medicinal chemistry , stereochemistry , crystallography , inorganic chemistry , catalysis , organic chemistry , crystal structure
Unable to elaborate (η 5 ‐C 5 H 5 )Fe(CO) 2 C(O)Ph by the nucleophile/electrophile sequences, the treatment of nucleophile PhLi followed by Lewis base 2,2′‐bipyridine instead leads to the meaningful isolation of [(η 5 ‐C 5 H 5 )Fe(CO) {C(O)Ph} 2 ] 2 Li 2 (2,2′‐bipyridine).