Spectrophotometric Determination of Palladium(II) with New Re Agent N‐octyl‐N′‐(Sodium P‐Amminobenzenesulfonate)Thiourea (OPT) | Zendy

Ma DongLan | Zendy; Li Ying | Zendy; Ltf QuanJian | Zendy; Wang YuLu | Zendy

Premium

Spectrophotometric Determination of Palladium(II) with New Re Agent N‐octyl‐N′‐(Sodium P‐Amminobenzenesulfonate)Thiourea (OPT)

Author(s) -

Ma DongLan,

Li Ying,

Ltf QuanJian,

Wang YuLu

Publication year - 2001

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.200100164

Subject(s) - chemistry , thiourea , palladium , reagent , molar absorptivity , ammonium bromide , color reaction , selectivity , buffer solution , bromide , absorption (acoustics) , sodium , nuclear chemistry , catalysis , inorganic chemistry , chromatography , pulmonary surfactant , organic chemistry , biochemistry , physics , acoustics , optics

The color reaction of palladium(II) with the new reagent OPT was studied. In the presence of cetyltrimethyl ammonium bromide (CTMAB), in pH 5.0–5.6 HAc‐NaAc buffer solution, a yellow‐brown soluble complex with the ratio of 1:4 was formed. The maximum absorption was at 299.0 nm, the apparent molar absorptivity ϵ 299.0 nm = 1.38×10 5 l mol −1 cm −1 . Beer's law was obeyed in the range of 2–12 μg Pd(II)/25 mL. The method's sensitivity and selectivity were very good. It could be used to determine palladium(II) in a catalyst with satisfactory results.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research