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Cationic Phosphine‐imine ρodium(I) Complexes and Their Activity on Catalysis of Phenylacetylene Polymerization
Author(s) -
Reddy K. Rajender,
Lin ChiFeng,
Lee GeneHsiang,
Peng ShieMing,
Chen JwuTing,
Liu ShiuhTzung
Publication year - 2001
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200100146
Subject(s) - chemistry , phenylacetylene , cationic polymerization , phosphine , polymerization , polymer chemistry , rhodium , catalysis , aqueous solution , imine , solvent , photochemistry , polymer , organic chemistry
A series of phosphine‐imine rhodium(I) complexes have been prepared and characterized by both spectroscopic and X‐ray single crystal analyses. Their activity on catalytic polymerization of phenylacetylene is investigated. The study of the solvent effect on polymerization shows that aqueous medium can in crease the productivity of polymer.