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An Acid‐Catalyzed Fragmentation Reaction of a Triamine‐Linked Acridine Dimer
Author(s) -
Chou ShanYen,
Yin WeiKung
Publication year - 2001
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200100115
Subject(s) - chemistry , dimer , acridine , solvolysis , cleavage (geology) , fragmentation (computing) , catalysis , medicinal chemistry , photochemistry , stereochemistry , polymer chemistry , organic chemistry , geotechnical engineering , fracture (geology) , computer science , hydrolysis , engineering , operating system
An acid‐catalyzed cleavage of the C‐N ϵ bond from N ϵ ‐(2,3,4,5‐tetrahydroxyvaleryl) substituted side chain and/or its acetonide form of a triamine‐linked acridine dimer is de scribed. An envisaged multi‐neighboring group‐assisted solvolysis reaction mechanism is proposed.