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Theory of Medium‐Induced Optical Activities
Author(s) -
Hsu F. C.,
Kuo Y.T.,
Shiu Y.J.,
Liang K. K.,
Hayashi M.,
Chang T.C.,
Lin S. H.
Publication year - 2001
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200100095
Subject(s) - chemistry , octant (instrument) , dipole , molecule , symmetry (geometry) , computational chemistry , optics , physics , organic chemistry , geometry , mathematics
Abstract In this paper, using the dipole‐dipole interactions to de scribe the interaction between the system molecule and medium molecules, a theory of medium‐induced optical activity has been developed. We have shown that the symmetry technique can be used to determine the types of electronic states that can be involved in the medium‐induced optical activity and that the octant rule can be deduced by using our theory.