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An Efficient Synthetic Strategy for Introduction of C 3 ‐C 4 Double Bond into Eudesmane Skeleton: First Total Synthesis of (+)‐Chrysanthemol
Author(s) -
Chen Yonggang,
Zhou Gang,
Xiong Zhaoming,
Liu Lijun,
Li Yulin
Publication year - 2001
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200100042
Subject(s) - chemistry , double bond , skeleton (computer programming) , enantioselective synthesis , stereochemistry , one step , combinatorial chemistry , organic chemistry , catalysis , chemical engineering , computer science , programming language , engineering
The first enantioselective synthesis of (+)‐chrysanthemol 1 was carried out starting from (+)‐dihydrocarvone in ten steps. In our studies, a facile synthetic strategy has been developed for introduction of C 3 ‐C 4 double bond into a eudesmane skeleton.