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Colorimetric Determination of Seleniumin Various Environmental Samples
Author(s) -
Chatterjee Sukumar,
Pillai Ajai Kumar,
Gupta Vinay Kumar
Publication year - 2001
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200100006
Subject(s) - chemistry , iodine , selenium , molar absorptivity , reagent , rhodamine b , potassium iodate , iodide , nuclear chemistry , chromatography , color reaction , inorganic chemistry , organic chemistry , physics , photocatalysis , optics , catalysis
A new reagent system using rhodamine‐B dye for the determination of selenium is described. The method is based on the reaction of selenium with acidified potassium iodide to liberate iodine. The liberated iodine bleaches the pink colour rhodamine‐B, which is measured at 555 nm. Beer's law is obeyed over the concentration range of 1–10 μg of selenium final solution volume of 25 mL (0.04–0.4 ppm) and the apparent molar absorptivity and Sandell's sensitivity was found to be 1.96× 10 5 l mol −1 cm −1 and 0.0004 μg cm −2 , respectively. The method is simple, sensitive, and selective and is satisfactorily applied to micro‐level determination of selenium in various environmental and cosmetic samples.