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Ironcarbonyl‐Mediated Alkene Hydroamidation of 7‐Oxabenzonorbornadiene
Author(s) -
Sun ChiaHsing,
Ho TzayShiou,
Wang JuChun
Publication year - 2000
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200000042
Subject(s) - chemistry , alkene , nucleophile , medicinal chemistry , ene reaction , organic chemistry , catalysis
Iron carbonyl‐mediated alkene hydroamidation of 7‐oxabenzonorbornadiene was accomplished under very mild conditions as the result of nucleophilic attack of amines on iron‐coordinating CO to produce exo ‐5‐(alkylaminocarbonyl)‐7‐oxabenzobicyclo[2.2.1]hept‐2‐ene derivatives.