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Polyene Cyclization Promoted by the Cross Conjugated α‐Carbalkoxy Enone System. An Efficient Approach to Highly Functionalized Decalins
Author(s) -
Liu HsingJang,
Sun Daqing,
Shia KakShan
Publication year - 1999
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199900062
Subject(s) - chemistry , polyene , conjugated system , enone , stereoselectivity , decalin , organic chemistry , catalysis , polymer
The cross conjugated α‐carbalkoxy enone system was found to be an excellent promoter for polyene cyclization. Under mild conditions, the reaction occurred readily with a high degree of regio‐ and stereoselectivity. Based on this facile process, an efficient method for the construction of highly functionalized decalin derivatives has been developed.