Premium
Alkoxide‐Accelerated [1,3] Sigmatropic Shift of Bicyclo[3.2.1]oct‐6‐en‐2‐ols to 8‐ endo ‐Hydroxybicyclo[3.3.0]oct‐2‐en‐4‐ones
Author(s) -
Chen YehLong,
Chang ChiKang,
Chang NeinChen
Publication year - 1998
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199800098
Subject(s) - chemistry , alkoxide , bicyclic molecule , sigmatropic reaction , medicinal chemistry , organic chemistry , catalysis
Bicyclo[3.2.1]oct‐6‐en‐2‐ols 6 are shown to undergo [1,3] sigmatropic shift to afford 8‐ endo ‐hydroxy‐bicyclo[3.3.0]oct‐2‐en‐4‐ones 8 under the influence of potassium hydride.