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Ene Reaction with Pummerer‐Type Reaction Intermediate of 1‐[(2‐Methylthio)ethanoyl]pyrrolidine: A Novel Synthesis of Trichonine
Author(s) -
Sun KuoHui,
Wang HueyMin,
Chen LingChing
Publication year - 1998
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199800094
Subject(s) - chemistry , pyrrolidine , adduct , pummerer rearrangement , ene reaction , organic chemistry , catalysis , acetic anhydride
Pummerer‐type reaction intermediate 2 of 1‐[(2‐methylthio)ethanoyl]pyrrolidine (1) has been found to react with 1‐alkenes to afford ene adducts 3 . Trichonine 4 was synthesized from the adduct 3g .