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Synthesis and Crystal Structure of (η 2 ‐Olefin)( N ‐phenyl‐2,3‐dicarbomethoxy‐7‐azabenzonorbornadiene)Fe(CO) 2 Complexes
Author(s) -
Sun ChiaHsing,
Wu ShiaoYu,
Liou LinShu,
Wang JuChun
Publication year - 1998
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199800085
Subject(s) - chemistry , olefin fiber , crystal structure , trigonal bipyramidal molecular geometry , crystallography , trigonal crystal system , bipyramid , stereochemistry , organic chemistry , catalysis
The title compounds 2a‐f were obtained from photochemical substitution of 1 with alkenes as stable solids in moderate yields. X‐ray structure determination of 2c shows a distorted trigonal bipyramidal geometry with two cross iron‐coordinated olefins. Compounds 2a‐f represent a new type of (η 2 ‐monoolefin) 2 (R 3 N)Fe(CO) 2 .