Synthesis and Crystal Structure of (η 2 ‐Olefin)( N ‐phenyl‐2,3‐dicarbomethoxy‐7‐azabenzonorbornadiene)Fe(CO) 2  Complexes | Zendy

Sun ChiaHsing | Zendy; Wu ShiaoYu | Zendy; Liou LinShu | Zendy; Wang JuChun | Zendy

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Synthesis and Crystal Structure of (η 2 ‐Olefin)( N ‐phenyl‐2,3‐dicarbomethoxy‐7‐azabenzonorbornadiene)Fe(CO) 2 Complexes

Author(s) -

Sun ChiaHsing,

Wu ShiaoYu,

Liou LinShu,

Wang JuChun

Publication year - 1998

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199800085

Subject(s) - chemistry , olefin fiber , crystal structure , trigonal bipyramidal molecular geometry , crystallography , trigonal crystal system , bipyramid , stereochemistry , organic chemistry , catalysis

The title compounds 2a‐f were obtained from photochemical substitution of 1 with alkenes as stable solids in moderate yields. X‐ray structure determination of 2c shows a distorted trigonal bipyramidal geometry with two cross iron‐coordinated olefins. Compounds 2a‐f represent a new type of (η 2 ‐monoolefin) 2 (R 3 N)Fe(CO) 2 .

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