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Tandem Thermal Reactions for the Synthesis of Jasmonoids
Author(s) -
Ho TseLok,
Shyu KuoFeng
Publication year - 1998
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199800051
Subject(s) - chemistry , tandem , cyclopentanone , cyclopropane , thermal decomposition , pyrolysis , cleavage (geology) , cascade reaction , thermal , photochemistry , organic chemistry , ring (chemistry) , catalysis , thermodynamics , materials science , physics , geotechnical engineering , fracture (geology) , engineering , composite material
A tandem reaction tactic for the preparation of a jasmonoid intermediate consists of pyrolysis of a spiroannulated cyclopentanone. The thermal decomposition actually involves a retro‐Diels‐Alder reaction and a homo‐1,5‐hydrogen shift with cleavage of the cyclopropane unit.