Tandem Thermal Reactions for the Synthesis of Jasmonoids | Zendy

Ho TseLok | Zendy; Shyu KuoFeng | Zendy

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Tandem Thermal Reactions for the Synthesis of Jasmonoids

Author(s) -

Ho TseLok,

Shyu KuoFeng

Publication year - 1998

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199800051

Subject(s) - chemistry , tandem , cyclopentanone , cyclopropane , thermal decomposition , pyrolysis , cleavage (geology) , cascade reaction , thermal , photochemistry , organic chemistry , ring (chemistry) , catalysis , thermodynamics , materials science , physics , geotechnical engineering , fracture (geology) , engineering , composite material

A tandem reaction tactic for the preparation of a jasmonoid intermediate consists of pyrolysis of a spiroannulated cyclopentanone. The thermal decomposition actually involves a retro‐Diels‐Alder reaction and a homo‐1,5‐hydrogen shift with cleavage of the cyclopropane unit.

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