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Reactions of 6‐Tricyanovinyldihydroquinolines
Author(s) -
Lin WenChung,
Lin ShawTao,
Hsieh MonLin
Publication year - 1998
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199800031
Subject(s) - chemistry , chlorine , sodium methoxide , hydrochloric acid , yield (engineering) , sodium hydroxide , hydroxide , substitution reaction , substitution (logic) , ring (chemistry) , medicinal chemistry , methoxide , group (periodic table) , organic chemistry , photochemistry , methanol , materials science , computer science , metallurgy , programming language
Reactions of 6‐tricyanovinyldihydroquinoline with concentrated hydrochloric acid and methanolic sodium hydroxide yield chlorine substitution on the heterocyclic ring and methoxide substitution of the cyano group, respectively. The chlorine substitution via a radical process is initiated from the tricyanovinyl group by the irradiation of visible light.