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Ene Reaction of Pummerer‐Type Reaction Intermediate and Synthesis of Pellitorine
Author(s) -
Lin WeiShing,
Wang HucyMin,
Chen LingChing
Publication year - 1998
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199800027
Subject(s) - chemistry , pummerer rearrangement , adduct , ene reaction , acetic acid , organic chemistry , acetic anhydride , medicinal chemistry , catalysis
Pummerer‐type reaction intermediate 2 of α‐(methylthio)acetic acid ( 1 ) has been found to react with 1‐alkenes to afford ene adducts 3 . Pellitorine 5 was synthesized from the adduct 3d .
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