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Electrocatalytic Oxidation of Amines to Nitriles on a TEMPO‐modified Graphite Felt Electrode (TEMPO = 2,2,6,6‐tetramethylpiperidin‐1‐yloxyl)
Author(s) -
Kashiwagi Yoshitomo,
Kurashima Futoshi,
Kikuchi Chikara,
Anzai JunIchi,
Osa Tetsuo,
Bobbin James M.
Publication year - 1998
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199800023
Subject(s) - chemistry , graphite , electrode , selectivity , electrochemistry , inorganic chemistry , polymer chemistry , organic chemistry , catalysis
Preparative electrocatalytic oxidation of amines to nitriles was successfully achieved on a poly (acrylic acid)‐coated graphite felt electrode immobilizing 4‐ammo‐2,2,6,6‐tetramethylpiperidin‐1‐yloxyl in high selectivity (> 95%) and high current efficiency (> 92%).