Electrochemistry of Hypervalent Compounds. 6. Selective α‐Fluorination of Sulfides Using Electrogenerated Hypervalent  p ‐Methoxyiodobenzene Difluoride 1 | Zendy

Fuchigami Toshio | Zendy; Fujita Toshiyasu | Zendy; Higashiya Seiichiro | Zendy; Konno Akinori | Zendy

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Electrochemistry of Hypervalent Compounds. 6. Selective α‐Fluorination of Sulfides Using Electrogenerated Hypervalent p ‐Methoxyiodobenzene Difluoride 1

Author(s) -

Fuchigami Toshio,

Fujita Toshiyasu,

Higashiya Seiichiro,

Konno Akinori

Publication year - 1998

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199800022

Subject(s) - hypervalent molecule , chemistry , acetophenone , difluoride , electrochemistry , fluorine , thio , medicinal chemistry , xenon difluoride , atom (system on chip) , organic chemistry , electrode , reagent , catalysis , computer science , embedded system

Anodically generated hypervalent p ‐methoxyiodobenezene difluoride reacted with α‐(ary]thio)‐ and α‐(benzylthio)acetates, and α‐(phenylthio)acetophenone to provide the corresponding fluorinated compounds. In ail cases, a fluorine atom was introduced exclusively α to the ester or benzoyl group.

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