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Electrochemistry of Hypervalent Compounds. 6. Selective α‐Fluorination of Sulfides Using Electrogenerated Hypervalent p ‐Methoxyiodobenzene Difluoride 1
Author(s) -
Fuchigami Toshio,
Fujita Toshiyasu,
Higashiya Seiichiro,
Konno Akinori
Publication year - 1998
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199800022
Subject(s) - hypervalent molecule , chemistry , acetophenone , difluoride , electrochemistry , fluorine , thio , medicinal chemistry , xenon difluoride , atom (system on chip) , organic chemistry , electrode , reagent , catalysis , computer science , embedded system
Anodically generated hypervalent p ‐methoxyiodobenezene difluoride reacted with α‐(ary]thio)‐ and α‐(benzylthio)acetates, and α‐(phenylthio)acetophenone to provide the corresponding fluorinated compounds. In ail cases, a fluorine atom was introduced exclusively α to the ester or benzoyl group.