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Ene Reaction of Pummerer‐Type Reaction Intermediate and Synthesis of Achillea Amide
Author(s) -
Lee HueyJy,
Wang HueyMin,
Chen LingChing
Publication year - 1997
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199700074
Subject(s) - chemistry , achillea , adduct , amide , pummerer rearrangement , ene reaction , organic chemistry , catalysis , acetic anhydride , botany , biology
Pummerer‐type reaction intermediate 2 of methyl α‐(methylthio)acetate (1) has been found to react with 1‐alkenes to afford ene adducts 3 . Achillea amide 5 was synthesized from the adduct 3g .