Ferro‐and Antiferromagnetic Properties of Metal Complexes with Pyridine‐Substituted Nitronyl Nitroxide Radicals | Zendy

Wei HoHsiang | Zendy; Wong HongYue | Zendy; Lee GeneHsiang | Zendy; Wang Yu | Zendy

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Ferro‐and Antiferromagnetic Properties of Metal Complexes with Pyridine‐Substituted Nitronyl Nitroxide Radicals

Author(s) -

Wei HoHsiang,

Wong HongYue,

Lee GeneHsiang,

Wang Yu

Publication year - 1996

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199600038

Subject(s) - chemistry , antiferromagnetism , monoclinic crystal system , radical , crystallography , transition metal , metal , pyridine , magnetic susceptibility , ferromagnetism , crystal structure , oxide , inorganic chemistry , nitroxide mediated radical polymerization , inductive coupling , medicinal chemistry , condensed matter physics , organic chemistry , catalysis , physics , polymer , radical polymerization , engineering , electrical engineering , copolymer

The synthesis, crystal structure and magnetic properties of the non‐transition metals; Cd(II), Zn(II), Hg(II), Mg(II) and the transition metals; Co(II), Ni(II), Cu(II) complexes with 2‐(4‐pyridyl)‐4,4,5,5‐tetra‐methylimidazolinyl‐l‐oxy‐3‐oxide (NITpPy) are presented. The compounds of free radical NITpPy, HgCl 2 (NITpPy), and Zn(acac) 2 (NITpPy) crystallize in the same monoclinic system of space group C2/c. The magnetic properties of the temperature‐dependent magnetic susceptibility of NITpPy and its metal complexes are discussed according to the Heisenberg model. A weak ferromagnetic coupling in NITpPy and a weak antiferromagnetic coupling in the metal complexes have been revealed.

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