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Magnetic Properties of M 3 [Fe(Cn) 6 ] 2 Xh 2 O (M = Co (II), Ni(II), Cu(II), Zn(II))
Author(s) -
Shyu H. L.,
Lin S. N.,
Wei H. H.
Publication year - 1995
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199500106
Subject(s) - chemistry , magnetization , analytical chemistry (journal) , electron paramagnetic resonance , crystallography , mössbauer spectroscopy , nickel , magnetic susceptibility , magnetic hysteresis , spectral line , mössbauer effect , hysteresis , nuclear magnetic resonance , magnetic field , condensed matter physics , physics , organic chemistry , chromatography , quantum mechanics , astronomy
Compounds of the type M 3 [Fe(CN) 6 ] 2 XH 2 O (M = Co(II), Ni(II), Cu(II), and Zn(II)) were prepared and magnetic properties of their powders were investigated by means of EPR spectra, Mössbauer effect and magnetic susceptibility measurements. The temperature dependence of the magnetization for the complexes Co 3 [Fe(CN) 5 ] 2 ‐ 10H 2 O, Ni 3 [Fe(CN) 6 ] 2 ‐10H 2 O and Cu 3 [Fe(CN) 6 ] 2 ‐4H 2 O revealed that below the critical temperatures 15, 22 and 20 K respectively, these complexes have zero‐field magnetization. The magnetic hysteresis at 10 K for Co(II), Ni(II) and Cu(II) complexes was observed. Mössbauer spectra at 4.2 K for the compounds are discussed.