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Promotion of Oxidative Dehydrogenation by Cobalt Ions and the Synthesis of Trans ‐diaqua(C‐ meso ‐3,5,7,7,10,12,14,14‐octamethyl‐1,4,8,11‐tetraazacyclotetradeca‐1,4,8,11‐tetraene)cobalt(II) Perchlorate
Author(s) -
Chen BorHann,
Lai ChungYu,
Chung ChungSun,
Liao FenLing,
Wang SueLein
Publication year - 1994
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199400087
Subject(s) - dehydrogenation , chemistry , cobalt , diene , ion , oxidative addition , oxidative phosphorylation , crystal (programming language) , medicinal chemistry , stereochemistry , inorganic chemistry , catalysis , organic chemistry , biochemistry , computer science , programming language , natural rubber
Aerial dehydrogenation of the Iigand in (C‐ meso ‐3,5,7,7,10,12,14,14‐octamethyl‐1,4,8,11‐tetraazacyclotetradeca‐4, 11‐diene)cobalt(III) leads to yellow chunky crystals of trans ‐diaqua(C‐ meso ‐3,5,7,7,10,12,14,14‐octamcthyl‐1,4,8,11‐tetraazacyclotetradeca‐1,4,8,11‐tetraene)cobait(II)(1). The crystal structure of this complex was determined by xray crystallography and a mechanism of this reaction is proposed.