Promotion of Oxidative Dehydrogenation by Cobalt Ions and the Synthesis of  Trans ‐diaqua(C‐ meso ‐3,5,7,7,10,12,14,14‐octamethyl‐1,4,8,11‐tetraazacyclotetradeca‐1,4,8,11‐tetraene)cobalt(II) Perchlorate | Zendy

Chen BorHann | Zendy; Lai ChungYu | Zendy; Chung ChungSun | Zendy; Liao FenLing | Zendy; Wang SueLein | Zendy

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Promotion of Oxidative Dehydrogenation by Cobalt Ions and the Synthesis of Trans ‐diaqua(C‐ meso ‐3,5,7,7,10,12,14,14‐octamethyl‐1,4,8,11‐tetraazacyclotetradeca‐1,4,8,11‐tetraene)cobalt(II) Perchlorate

Author(s) -

Chen BorHann,

Lai ChungYu,

Chung ChungSun,

Liao FenLing,

Wang SueLein

Publication year - 1994

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199400087

Subject(s) - dehydrogenation , chemistry , cobalt , diene , ion , oxidative addition , oxidative phosphorylation , crystal (programming language) , medicinal chemistry , stereochemistry , inorganic chemistry , catalysis , organic chemistry , biochemistry , computer science , programming language , natural rubber

Aerial dehydrogenation of the Iigand in (C‐ meso ‐3,5,7,7,10,12,14,14‐octamethyl‐1,4,8,11‐tetraazacyclotetradeca‐4, 11‐diene)cobalt(III) leads to yellow chunky crystals of trans ‐diaqua(C‐ meso ‐3,5,7,7,10,12,14,14‐octamcthyl‐1,4,8,11‐tetraazacyclotetradeca‐1,4,8,11‐tetraene)cobait(II)(1). The crystal structure of this complex was determined by xray crystallography and a mechanism of this reaction is proposed.

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