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Bicyclo[3.2.1]octenones As Building Blocks in Natural Products Synthesis (III). Total Synthesis of (±)‐10‐Deoxygeniposide Aglucone
Author(s) -
Hsu LungFu,
Chang NeinChen
Publication year - 1994
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199400083
Subject(s) - chemistry , bicyclic molecule , yield (engineering) , enone , total synthesis , stereochemistry , metallurgy , materials science
The title compound was synthesized from bicyclo[3.2.1]octenone 1 in six steps and in overall yield 59%. Photochemical rearrangement of β,γ‐unsaturated enone 1 is the key step.