z-logo
Premium
Photochemistry of Syn‐ and Anti‐A8,9‐Dimethoxycarbonyl‐1,5‐Dipropyl‐3‐Oxatricyclo[3.2.2.0 2,4 ]Non‐8‐Ene‐6,7‐Dione
Author(s) -
Liao ChunChen,
Lin HoShen,
Tsai YowFu,
Ueng YihGang
Publication year - 1993
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199300079
Subject(s) - chemistry , ene reaction , photochemistry , medicinal chemistry , stereochemistry
In the photochemistry of the title compounds, the anti isomer 6 afforded oxepine 9 whereas the syn isomer yielded 9 and 10 ; the reactions proceeded partly via cyclobutanediones 12 and 13 . The distinct photochemical behavior are explained in terms of stereorelectronic effects of the epoxy rings.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here