Preparation of Palladium(II) and Platinum(II) Phosphine Complexes Promoted by Phase‐Transfer Catalysts | Zendy

Lin Ivan J. B. | Zendy; Liaw Miles D. S. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Preparation of Palladium(II) and Platinum(II) Phosphine Complexes Promoted by Phase‐Transfer Catalysts

Author(s) -

Lin Ivan J. B.,

Liaw Miles D. S.

Publication year - 1993

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199300071

Subject(s) - chemistry , phosphine , palladium , catalysis , platinum , aryl , medicinal chemistry , phase (matter) , nmr spectra database , alkyl , proton nmr , polymer chemistry , spectral line , stereochemistry , organic chemistry , physics , astronomy

The synthesis of M(PR 3 ) 2 Cl 2 (M = Pd and Pt, R = alkyl or aryl) front K 2 MCl 4 (in H 2 O) and PR 3 (in CH 2 Cl 2 ) was promoted by the addition of phase‐transfer catalysts (PTC). The greater the amount of PTC used, the more quickly the reaction completed. 31 P NMR spectra of some M(PR 3 ) 2 Cl 2 in the presence of free PR 3 were measured; these NMR resulls were used to explain problems encountered during the preparations.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research