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The Reaction of 4‐Formylsydnone and Methyl Ketones
Author(s) -
Hung WeiJing,
Tien HsienJu,
Chou TzooMing,
Tien LingLing,
Wu ChengKwei
Publication year - 1993
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199300060
Subject(s) - chemistry , acetophenone , ketone , acetone , base (topology) , methyl ketone , organic chemistry , medicinal chemistry , catalysis , mathematics , mathematical analysis
In the presence of base, 3‐subslituted 4‐fonnyl‐ and 4‐acetylsydnones decarbonylated to afford the corresponding 3‐substituted sydnones. The Claisen‐Schmidt reaction occurred between 3‐substituted 4‐for‐mylsydnones and methyl ketone (such as 4‐acetylsydnones, acetone and acetophenone) in dilute basic solution or electrogenerated basic (EGB) solution.