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A Tri‐Coordinate‐Magnesium Silylamide Complex: {[(CH 3 ) 3 Si] 2 N} 2 MgO(CH 2 CH 2 ) 2 OMg{N[Si(CH 3 ) 3 ] 2 } 2
Author(s) -
Her TzongYih,
Chang ChungCheng,
Lee GeneHsiang,
Feng ShieMing,
Wang Yu
Publication year - 1993
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199300048
Subject(s) - chemistry , adduct , magnesium , solid state , oxygen atom , crystallography , inorganic chemistry , medicinal chemistry , molecule , organic chemistry
The reaction of diethylmagnesium dioxane adduct solution with 1,1,1,3,3,3‐hexamethyldisilazan ((CH 3 ) 3 SiNHSi(CH 3 ) 3 ) gives {[(CH 3 ) 3 Si] 2 N} 2 MgO(CH 2 CH 2 ) 2 OMg{N[Si(CH 3 ) 3 ] 2 } 2 (1); this alkoxomagnesium silylamide in the solid state contains unprecedented three‐coordinate magnesium and oxygen atoms.