Premium
Mössbauer and Magnetic Studies on the Spin‐State Transitions of Iron Complexes
Author(s) -
Wei HoHsiang
Publication year - 1992
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199200089
Subject(s) - chemistry , spin crossover , spin states , mössbauer spectroscopy , spin (aerodynamics) , spin transition , ion , condensed matter physics , crystallography , state (computer science) , inorganic chemistry , thermodynamics , physics , organic chemistry , algorithm , computer science
Abstract Mössbauer and magnetic studies on the spin‐state transitions in various complexes of iron(II) and iron(III) ions have received considerable attention. The present account deals with some examples of the effects of intraligand substitution and sample size on the spin‐state transitions of 5 T 2 ↔ 1 A 1 for iron(II) and 6 A 1 ↔ 2 T 2 for Iron(III)‐complexes. A new instance of 3 T 1 ↔ 5 T 2 spin‐crossover Fe(II)‐complex is reported.