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A Facile Diagnostic 1 H NMR Method for Syn and anti Hydroxy Systems
Author(s) -
Roos Gregory H. P.,
Manickum Thavrin,
Malissar Dean G.
Publication year - 1992
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199200016
Subject(s) - chemistry , computational chemistry
In diastereomeric hydroxyl‐containing systems, the relative 1 H‐NMR chemical shift of the carbamate NH of the in situ generated trichloroacetylisocyanate derivatives appear to be diagnostic for the syn and anti stereochemistry.