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Synthesis and Coordination of Tripodal‐Containing Copper(I) Complexes
Author(s) -
Wang HsinEll,
Liu ShiuhTzung,
Lee GeneHsian,
Cheng MingChu,
Peng ShieMing
Publication year - 1991
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199100093
Subject(s) - chemistry , acetonitrile , copper , chloroform , recrystallization (geology) , crystal structure , chloride , metal , copper(ii) chloride , coordination complex , inorganic chemistry , crystallography , silver nitrate , medicinal chemistry , stereochemistry , nuclear chemistry , organic chemistry , paleontology , biology
Reaction of copper(I) chloride with 2,2‐bis(diphenylphosphinomethyl)‐l‐phenylthiopropane P 2 S produced a dimeric species [(P 2 S)CuC1] 2 (2). Treatment of 2 with silver nitrate in acetonitrile gave a hexameric crystalline metal complex {[(P 2 S)Cu(CH 3 CN)] 6 + 6NO 3 } (4), which had a “cyclodextrin‐type” structure. A linear polymeric copper complex [(P 2 S)Cu(NO 3 )] n was obtained by recrystallization of 4 in chloroform. These complexes were characterized by single crystal analyses, and their coordination behaviors in solution are discussed.