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Reaction of Tricarbonyl(η 3 ‐allyl)iron(0) Anions with Bromine
Author(s) -
Yeh MingChang P.,
Kang KuoPing,
Hwu ChongChen
Publication year - 1991
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199100079
Subject(s) - chemistry , bromine , carbanion , diene , nucleophile , reactive intermediate , medicinal chemistry , photochemistry , ion , nucleophilic addition , organic chemistry , catalysis , natural rubber
The addition of reactive carbanions to tricarbonyl(η 4 ‐1,3‐diene)iron(0) complexes proceeded at 23°C to give putative tricarbonyl(η 3 ‐allyl)iron(0) anion complexes. Trapping of the reactive intermediates with bromine produced nucleophilic‐substituted tricarbonyl(η 4 ‐1,3‐diene)iron(0) complexes.