The Flash Vacuum Thermolysis of  N ‐Acyl Imidates | Zendy

Wu PeiLin | Zendy; Wang ChingCheng | Zendy

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The Flash Vacuum Thermolysis of N ‐Acyl Imidates

Author(s) -

Wu PeiLin,

Wang ChingCheng

Publication year - 1991

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199100045

Subject(s) - chemistry , thermal decomposition , intramolecular force , flash (photography) , cycloaddition , photochemistry , flash vacuum pyrolysis , methanol , thermal , organic chemistry , pyrolysis , thermodynamics , catalysis , art , visual arts , physics

In the flash vacuum thermolysis of methyl N ‐acyl imidates, the loss of methanol is consistent with the intermediacy of an N ‐acylketenimine. Recombination and further reactions may lead to the array of products observed in these thermal reactions. An attempt to trap the intermediate N ‐acylketenimine by an intramolecular [2 + 2] cycloaddition was unsuccessful.

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