Mössbauer Spectroscopic Studies of Ferrocenylaldimines and their TCNQ Complexes | Zendy

Lee ChinJhan | Zendy; Wei HoHsiang | Zendy

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Mössbauer Spectroscopic Studies of Ferrocenylaldimines and their TCNQ Complexes

Author(s) -

Lee ChinJhan,

Wei HoHsiang

Publication year - 1991

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199100023

Subject(s) - chemistry , mössbauer spectroscopy , condensation , schiff base , oxidation state , base (topology) , crystallography , organic chemistry , metal , physics , thermodynamics , mathematical analysis , mathematics

A series of ferrocenylaldimines (Fc‐CH=N‐R) has been prepared by Schiff base condensation of formylferrocene with polyacenylamines RNH 2 where R = naphthyl, 5,6,7,8‐tetrahydronaphthyl, anthracenyl, and pyrenyl groups. This step was followed by oxidation with TCNQ to give [Fc‐CH = N‐R][TCNQ] 2 salts. The electronic state of iron in these compounds was investigated by means of 57 Fe Mössbauer spectroscopy.

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