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Application of Pulsed Field Gradients in High‐Resolution NMR Spectroscopy
Author(s) -
Doddrell David M.
Publication year - 1991
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199100018
Subject(s) - chemistry , nuclear magnetic resonance spectroscopy , resolution (logic) , spectroscopy , field (mathematics) , high resolution , transverse relaxation optimized spectroscopy , analytical chemistry (journal) , spectral line , two dimensional nuclear magnetic resonance spectroscopy , nmr spectra database , fluorine 19 nmr , nuclear magnetic resonance , organic chemistry , stereochemistry , physics , computer science , quantum mechanics , remote sensing , mathematics , artificial intelligence , pure mathematics , geology
In this paper the applicability of pulsed field gradients in high‐resolution NMR spectroscopy are considered. Applications include solvent suppression, spectral editing of one‐ and two‐dimensional (2D) NMR spectra and the induction of quadrature detection in the w 1 , direction of many 2D experiments. The applications are analysed using simple product operator algebra. Particular attention is directed to discussing the experimental requirements of this technology in order that high‐resolution NMR conditions are maintained throughout the experiment.