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Study on the Nucleophilic Addition to (η 4 ‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex
Author(s) -
Yeh MingChang P.,
Chu ChihHong,
Sun MeiLing,
Kang KuoPing
Publication year - 1990
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.199000075
Subject(s) - chemistry , carbanion , 1,3 butadiene , adduct , quenching (fluorescence) , nucleophilic substitution , medicinal chemistry , nucleophilic addition , substitution reaction , nucleophile , photochemistry , organic chemistry , fluorescence , catalysis , physics , quantum mechanics
Reaction of the reactive carbanion with (η 4 ‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.