Study on the Nucleophilic Addition to (η 4 ‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex | Zendy

Yeh MingChang P. | Zendy; Chu ChihHong | Zendy; Sun MeiLing | Zendy; Kang KuoPing | Zendy

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Study on the Nucleophilic Addition to (η 4 ‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex

Author(s) -

Yeh MingChang P.,

Chu ChihHong,

Sun MeiLing,

Kang KuoPing

Publication year - 1990

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.199000075

Subject(s) - chemistry , carbanion , 1,3 butadiene , adduct , quenching (fluorescence) , nucleophilic substitution , medicinal chemistry , nucleophilic addition , substitution reaction , nucleophile , photochemistry , organic chemistry , fluorescence , catalysis , physics , quantum mechanics

Reaction of the reactive carbanion with (η 4 ‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.

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