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Preparation of Poly( p ‐Phenylene), Poly( m ‐Phenylene), and Poly(2,5‐Thienylene) Via Electron Transfer from Aryl Grignard Reagents to 2,3‐Dichloropropene
Author(s) -
Luo FenTair
Publication year - 1988
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.198800064
Subject(s) - chemistry , phenylene , bromide , reagent , polymer chemistry , poly(p phenylene) , aryl , grignard reagent , vinyl bromide , polymer , electron transfer , organic chemistry , alkyl
Three polymers including poly(p‐phenylene), poly(m‐phenylene), and poly(2,5‐thienylene) were synthesized in good yields from the corresponding aryldimagnesium bromide with two equiv of 2,3‐dichloropropene. The polymerization process involving electron transfer from the Grignard reagent to 2,3‐dichloropropene is proposed.