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An Unprecedented Oxidation Reaction of Cyclopentadiene Derivatives by Pyridinium Chlorochromate
Author(s) -
Wu HsienJen,
Pan Kai,
Hsia KetShang,
Liu WeiChi
Publication year - 1988
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.198800033
Subject(s) - pyridinium chlorochromate , chemistry , cyclopentadiene , furan , pyridinium , organic chemistry , alkyl , catalysis
Oxidation of the furan cyclopentadienes (2) and (4) with pyridinium chlorochromate gave the cyclopentenones (5) and (6) respectively. Oxidation of the alkyl cyclopentadienes (7a and 7b) also gave the corresponding cyclopentenones (8a and 8b) as the major products.