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A Theoretical Analysis of Single Drop Square‐Wave Polarography
Author(s) -
Hwang JinYih,
Wang YungYun,
Wan ChiChao
Publication year - 1986
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.198600043
Subject(s) - polarography , chemistry , square wave , planar , drop (telecommunication) , diffusion current , diffusion , square (algebra) , analytical chemistry (journal) , thermodynamics , current (fluid) , voltage , chromatography , geometry , quantum mechanics , electrical engineering , physics , computer graphics (images) , computer science , engineering , mathematics
The peak current response to single drop square‐wave polarography (SDSWP) is developed based on a spherical diffusion model. It is found that the equation originally developed by Ramaley et al. based on a planar diffusion model is only a special case of the generalized model.