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Preparation of σ‐ and π‐Benzyl Type Derivatives of Molybdenum
Author(s) -
Lin See,
Lin C. Y.,
Wang H. Y.
Publication year - 1986
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.198600036
Subject(s) - chemistry , molybdenum , derivative (finance) , hexane , medicinal chemistry , organic chemistry , economics , financial economics
The reaction of ‐LiM 0 (CO) 2 Cp with α‐chloromethylnaphthalene gives a yellow, crystalline σ‐benzyl type derivative of molybdenum (1). Irridation of (1) in n ‐hexane gives a red π‐benzyl type derivative (2). Both complexes (1) and (2) are stable in air.