Mixed Ligand Complexes of Palladium (II) with Diethylenetriamine as Primary Ligand and Peptides as Secondary Ligand | Zendy

Soukry Mohamed M. | Zendy; Darwish N. A. | Zendy; Hosny W. M. | Zendy

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Mixed Ligand Complexes of Palladium (II) with Diethylenetriamine as Primary Ligand and Peptides as Secondary Ligand

Author(s) -

Soukry Mohamed M.,

Darwish N. A.,

Hosny W. M.

Publication year - 1986

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.198600023

Subject(s) - chemistry , diethylenetriamine , palladium , ligand (biochemistry) , chelation , titration , stability constants of complexes , stereochemistry , inorganic chemistry , medicinal chemistry , polymer chemistry , organic chemistry , ion , catalysis , biochemistry , receptor

Solution equilibria of the system palladium (II)‐diethylenetriamine ( dien ) and peptides have been studied. The p H‐metric titration of the reaction mixture containing equimolar solutions of palladium (II), dien and peptide have shown the formation of 1:1:1 mixed ligand complex. The pK e of the peptides studied and formation constants of the resulting complexes have been determined at 25° C . The mode of chelation has been deduced from the conductivity measurements.

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